DISSOLUTION AND PRECIPITATION OF ZINC AND MANGANESE OBTAINED FROM SPENT ZINC-CARBON AND ALKALINE BATTERY POWDER

KURŞUNOĞLU S., KAYA M.

PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING, cilt.50, sa.1, ss.41-55, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 50 Sayı: 1
  • Basım Tarihi: 2014
  • Doi Numarası: 10.5277/ppmp140104
  • Dergi Adı: PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.41-55
  • Anahtar Kelimeler: leaching, ascorbic acid, manganese, zinc, precipitation, LIQUID-LIQUID-EXTRACTION, HYDROMETALLURGICAL ROUTE, RECOVERY, ACID, SEPARATION, REDUCTANT, ORE, DIOXIDE
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

The aim of this study was to investigate manganese and zinc recoveries from spent zinc-carbon and alkaline battery powder. The effect of sulfuric acid concentration, ascorbic acid dosage, reaction temperature and leaching time on zinc and manganese dissolutions was investigated. The optimum reductive acid leaching conditions were determined as: 3 hours, 70 degrees C, 0.5 M of sulfuric acid concentration, 13 g/dm(3) of ascorbic acid dosage, 1/20 g/cm(3) of solid/liquid ratio and 200 rpm of stirring speed. Under these conditions, dissolution efficiencies were 99.99% for Zn and 99.25% for Mn. In addition, dissolution kinetics of manganese was undertaken, and the activation energy was found to be 7.04 kJ/mol. Using 3 M NaOH as precipitating agent at room temperature, 95.35% of Zn (at pH 8) and 93.66% of Mn (at pH 10) were precipitated from the leaching solution. Under the same conditions, using 3 M KOH, precipitations of Zn and Mn were 91.63% and 96.39%, respectively. Based on the experimental results, a flowsheet of zinc and manganese recovery was proposed.