Apparent molar volume and apparent molar isentropic compressibility of glycerol in fructose-water at different temperatures

SAVAROĞLU G., Ozdemir M.

JOURNAL OF MOLECULAR LIQUIDS, cilt.137, ss.51-57, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 137
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.molliq.2007.03.007
  • Dergi Adı: JOURNAL OF MOLECULAR LIQUIDS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.51-57
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Speed of sound and densities of water+fructose+glycerol, at different concentrations in the temperature range 298.15 to 313.15 K, at 5 K intervals, have been experimentally determined. Apparent molar volumes and isentropic compressibilities, and apparent molar isentropic compressibilities have been calculated from density and speed of sound data. These results have been used to calculate the following partial molar quantities and temperature derivatives as a function of temperature: K-phi(0), (partial derivative K-2,m(0)/partial derivative T)(P), (partial derivative K-2(2,m)0/partial derivative T-2)(P), V-phi(0), (partial derivative V-phi(0)/partial derivative T)(P), and (partial derivative V-2(phi)0/partial derivative T-2)(P). The results are discussed in the light of solute-solvent and solute-solute interactions. (C) 2007 Elsevier B.V. All rights reserved.