THE ROLE OF DEPOSITION TEMPERATURE ON PARTICLE SIZE, ROUGHNESS PARAMETERS, MAGNETIC AND STRUCTURAL FEATURES OF ELECTROCHEMICALLY GROWN Ni-Fe/ITO SAMPLES

Saraç U., Kaya M., Baykul M. C.

DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, cilt.16, sa.1, ss.51-60, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 16 Sayı: 1
  • Basım Tarihi: 2021
  • Dergi Adı: DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Central & Eastern European Academic Source (CEEAS), Directory of Open Access Journals
  • Sayfa Sayıları: ss.51-60
  • Anahtar Kelimeler: Ni-Fe/ITO samples, Structural features, Deposition temperature, Particle size, Roughness parameters, Coercive force, Squareness, FE THIN-FILMS, NANOCRYSTALLINE NI, MICROSTRUCTURAL PROPERTIES, COMPOSITE COATINGS, SACCHARIN ADDITION, BATH TEMPERATURE, INTERNAL-STRESS, GRAIN-SIZE, ALLOYS, ELECTRODEPOSITION
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In this work, the impact of the deposition temperature (DT) on the particle size, roughness parameters, coercive force, squareness and structural features of the Ni-Fe samples electrochemically deposited onto glasses covered with indium tin oxide (ITO) was researched. An increase in the DT from 20 to 40 degrees C led to a very slight increase in the Fe concentration of the samples, revealing that the effect of the DT on the chemical composition was insignificant. The crystal structure was a face-centered cubic (fcc) and the preferred growth orientation was in the [111] direction irrespective of the DT. The crystallization of the samples improved, the size of the crystallites increased and the strength of the [111] growth orientation diminished with the DT. An increment in the DT resulted in a strong enhancement in the particle size and surface roughness. Further surface analysis indicated that the sample surface had a well spread out height distribution at the DT of 40 degrees C, while the sample surfaces at lower DTs 20 and 30 degrees C had narrow height distributions. In addition to that, the peaks were found to be predominant on the sample surfaces at lower DTs (20 and 30 degrees C), whereas the deep valleys were predominant on the sample surface at the DT of 40 degrees C. Magnetic measurements confirmed the existence of a semi-hard magnetic property in all samples. Compared to other samples produced at lower DTs (20 and 30 degrees C), the Ni-Fe sample electroplated at the DT of 40 degrees C possessed the highest coercive force and squareness values. Moreover, the magnetic characteristics of the samples were compatible with their morphological and structural characteristics.