Catalytic pyrolysis of Paulownia wood and bio-oil characterization


YILDIZ D., Yorgun S.

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, cilt.46, sa.1, ss.1626-1643, 2024 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 46 Sayı: 1
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/15567036.2023.2289563
  • Dergi Adı: ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, ABI/INFORM, Aerospace Database, Agricultural & Environmental Science Database, Applied Science & Technology Source, CAB Abstracts, Communication Abstracts, Compendex, Computer & Applied Sciences, Environment Index, Greenfile, INSPEC, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1626-1643
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

This study focused on the catalytic pyrolysis of Paulownia (P. elongota) wood. The effects of ZSM-5, Na2CO3, sepiolite, and catalyst ratio (10-80% by wood weight) on product yields and bio-oil composition were investigated. In pyrolysis experiments, 500 degrees C pyrolysis temperature, 50 degrees C min(-1) heating rate, and 100 mL min(-1) N-2 flow rate were kept as constant. The catalyst type and catalyst ratio changed the product yields and bio-oil compositions. Pyrolysis conversion was increased for all catalyst types. Maximum liquid product yields were obtained as 63.26 wt%, 56.18 wt%, and 54.59 wt% with the ZSM-5, Na2CO3 and sepiolite, respectively, at 10 wt% catalyst ratio. For all catalysts, it was determined that the liquid and solid yields reduce and the gas product yield rises with the catalyst ratio. The bio-oil characterization was performed with elemental analysis, FTIR, (HNMR)-H-1, and GC-MS techniques. The bio-oil composition was determined to consist of alkanes, carboxylic acids, ketones, esters, benzenes, and phenols.