[N-(2-Hydroxyethyl)ethylenediamine]oxalatocopper(II)

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Pasaoglu H., Kastas G., YEŞİLEL O. Z., Yildirim M. H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.65, 2009 (SCI-Expanded, ESCI, Scopus)

• Publication Type: Article / Article
• Volume: 65
• Publication Date: 2009
• Doi Number: 10.1107/s1600536809040264
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
• Open Archive Collection: AVESIS Open Access Collection
• Eskisehir Osmangazi University Affiliated: Yes

Abstract

In the title mononuclear copper(II) compound, [Cu(C2O4)(C4H12N2O)], the Cu-II ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxyethyl) ethylenediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex molecules participate in a supramolecular assembly through N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds between HydEt-en and ox ligands.