[N-(2-Hydroxyethyl)ethylenediamine]oxalatocopper(II)

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Pasaoglu H., Kastas G., YEŞİLEL O. Z., Yildirim M. H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.65, 2009 (SCI-Expanded, ESCI, Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 65
• Basım Tarihi: 2009
• Doi Numarası: 10.1107/s1600536809040264
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
• Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
• Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In the title mononuclear copper(II) compound, [Cu(C2O4)(C4H12N2O)], the Cu-II ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxyethyl) ethylenediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex molecules participate in a supramolecular assembly through N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds between HydEt-en and ox ligands.