Diapuabis(1,10-phenanthroline)cobalt(II) diorotate 2.25-hydrate

Bulut, A; Icbudak, H; YEŞİLEL, OKAN; Olmez, H; Buyukgungor, O

doi:10.1107/s1600536803017161

Diapuabis(1,10-phenanthroline)cobalt(II) diorotate 2.25-hydrate

Atıf İçin Kopyala

Bulut A., Icbudak H., YEŞİLEL O. Z., Olmez H., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.59, 2003 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 59
Basım Tarihi: 2003
Doi Numarası: 10.1107/s1600536803017161
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
Eskişehir Osmangazi Üniversitesi Adresli: Hayır

Özet

In the title compound, [Co(C12H8N2)(2)(H2O)(2)](C5H3N2O4)(2) .2.25H(2)O, the cobalt cation, located on a twofold axis, is coordinated by two symmetry-related aqua ligands together with a pair of symmetry-related bidentate phenanthroline ( phen) molecules, and exhibits a distorted octahedral coordination. The unique orotate anion in the asymmetric unit has a single negative charge. The coordinated water molecules link the orotate ions to the metal complex via O-H...O hydrogen bonds. Each uncoordinated water molecule is hydrogen bonded to orotate ions through O-H...O hydrogen bonds.