Tris(1,10-phenanthroline)nickel(II) squarate octahydrate
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.61, 2005 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 61
- Publication Date: 2005
- Doi Number: 10.1107/s1600536805012055
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Eskisehir Osmangazi University Affiliated: No
Abstract
In the title mononuclear [Ni(phen)(3)] sq center dot 8H(2)O complex [phen is 1,10-phenanthroline (C12H8N2) and sq is squarate (C4O42-)], the Ni-II ion has a distorted octahedral coordination geometry composed of six N atoms from three bidentate chelating phen ligands. An extensive three-dimensional network of O-water - H center dot center dot center dot O, O-water - H center dot center dot center dot O-water and C-H center dot center dot center dot O hydrogen-bonding interactions is responsible for crystal stabilization.