Carbon nano tube assisted triple metal electrode and high-impact electro sensor for preservative detection in food samples


Yayla M., Çelik Kazıcı H., DEMİR KIVRAK H.

Materials Research Innovations, cilt.28, sa.5, ss.309-320, 2024 (Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 28 Sayı: 5
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/14328917.2023.2280864
  • Dergi Adı: Materials Research Innovations
  • Derginin Tarandığı İndeksler: Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Chemical Abstracts Core, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.309-320
  • Anahtar Kelimeler: Benzoic acid, food sensor, potassium sorbate
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In this study, the electrode surface was modified with ternary metal supported by carbon nanotubes and for this purpose, PdRuCr-based sensor was developed that determines the preservatives in different food. The surfaces electronic and chemical properties were determined by methods such as SEM-EDX (scanning electron microscopy, Energy-Emitting X-ray analysis) and XRD (X ray diffraction). The activities of the electrocatalyzers were carried out using electrochemical measurements such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. The lowest limit ranges (LOD) were determined. For benzoic acid (BA) and potassium sorbate (PS), the specification limit values of the sensors were calculated as 0.82 µM (0.1 mgL−1 in ppm) and and 11.9 µM (1.78 mgL−1 in ppm) respectively. The sensitivity of the sensor was calculated as 1123,944 µA/mM.cm2 for BA and 2363,38 µA/mM.cm2 for PS and linear concentration range were determined as 2.5–200 µM for BA and 35–140 µM for PS, respectively.