Hydrazine electrooxidation performance of cyano-substituted indole derivatives as organic anode catalyst

Çalış Karatekin H., Ulaş B., Yilmaz Y., DEMİR KIVRAK H., KIVRAK A.

Process Safety and Environmental Protection, cilt.186, ss.1410-1418, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 186
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1016/j.psep.2024.04.085
  • Dergi Adı: Process Safety and Environmental Protection
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Environment Index, Food Science & Technology Abstracts, Greenfile, INSPEC, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1410-1418
  • Anahtar Kelimeler: Electrooxidation, Energy, Fuel cell, Hydrazine, Indoles
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Here we present the new EWG-substituted indole derivatives, namely 2-((5-(1-methyl-2-phenyl-1 H-indol-3-yl)thiophen-2-yl)methylene) malonitrile (IPTM), 2-((5-(1-methyl-2-phenyl-1 H-indol-3-yl)furan-2yl)methyl)malonitrile(IPFM) and 2-((4-(1-methyl-2-phenyl-1 H-indol-3-yl)benzylidene) malonitrile (IPPM) was synthesized by using Sonogashira coupling, electrophilic cyclization, Suzuki-Miyaura coupling and condensation reactions. The isolated yields were obtained as 86 %, 71 %, and 69 % yields, respectively. Cyclic voltammetry(CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) were used for the electrochemical measurements to observe the electrocatalytic behavior of IPTM, IPFM and IPPM. The results exhibited that the highest-performance organic-based catalyst was 2.601 mA/cm2 (0.073 mA/mg) for IPPM which could be a good candidate as a metal-free electrocatalyst for hydrazine electrooxidation.