Product operator theory for spin-3/2 nuclei and application to 2D J-resolved NMR spectroscopy

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Gencten A., Tezel Ö., Bahceli S.

CHEMICAL PHYSICS LETTERS, vol.351, pp.109-114, 2002 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 351
  • Publication Date: 2002
  • Doi Number: 10.1016/s0009-2614(01)01270-2
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.109-114
  • Eskisehir Osmangazi University Affiliated: No


The detailed description of the product operator formalism for a weakly coupled IS (I = 1/2, S = 3/2) spin system has been presented and the shorthand notations for the evolutions of I-x, I-y, IxSz and IySz product operators under the spin-spin coupling Hamiltonian have been obtained in a different form. Furthermore, as an application and a verification, the product operator formalism has been used for the analytical description of a 2D J-resolved nuclear magnetic resonance (NMR) experiment for IS (I = 1/2, S = 3/2) spin systems. (C) 2002 Elsevier Science B.V. All rights reserved.