A porous Zn(II)-coordination polymer based on a tetracarboxylic acid exhibiting selective CO2 adsorption and iodine uptake

ARICI M., Arici T. A., Demiral H., TAŞ M., YEŞİLEL O. Z.

DALTON TRANSACTIONS, cilt.49, sa.31, ss.10824-10831, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 49 Sayı: 31
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0dt01875a
  • Dergi Adı: DALTON TRANSACTIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aquatic Science & Fisheries Abstracts (ASFA), Chimica, Communication Abstracts, Compendex, EMBASE, MEDLINE
  • Sayfa Sayıları: ss.10824-10831
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

A porous Zn(II)-coordination polymer, namely {[Zn-2(mu(8)-abtc)(betib)]center dot DMF}(n) (1), was solvothermally synthesized from 3,3',5,5'-azobenzenetetracarboxylate (abtc(4-)) and 1,4-bis(2-ethylimidazol-1-yl)butane (betib) ligands and {[Zn-2(mu(8)-abtc)(betib)]center dot H2O}(n) (2) was obtained through the immersion of 1 in methanol. Compounds 1 and 2 were structurally characterized via numerous techniques. Both compounds displayed a 3D porous framework with a 3,6-connected sqc5381 net. Compound 2a obtained at 140 degrees C from 2 exhibited gas and iodine adsorption properties. Interestingly, the compound adsorbed selectively CO2 with the uptake capacity of 54.02 cm(3) g(-1) (13.26%) over N-2 (5.43 cm(3) g(-1)) and CH4 (14.53 cm(3) g(-1)) at 273 K. The compound also adsorbed iodine with the weights of 19.99% and 30.26% in solution and vapor phases, respectively. The single crystal X-ray result and Raman spectra showed the presence of iodine units in the pores of the framework.