The Effects of Exfoliation on the Clay / Polymer Nanocomposites Hydrogel Structure


Yıldız E., KURAMA H.

European Metallurgical Conference EMC 2021, Almanya, 27 Haziran 2021, cilt.1, ss.389-406

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Cilt numarası: 1
  • Basıldığı Ülke: Almanya
  • Sayfa Sayıları: ss.389-406
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Hydrogels are the polymeric materials that characterized by three-dimensional, cross-linked, and flexible

polymer networks. The hydrophilic groups within structure such as hydroxyl, carboxyl, and amide

that allow it swell in water and hold a large amount of water while maintaining the structure due

to chemical or physical cross-linking of individual polymer chains. Owing to their advantageous

properties, such as swellability, bio-compatibility, lack of toxicity and low production costs hydrogels

have been utilized in a wide range of hygienic, agricultural, medical, environmental protection and

pharmaceutical applications. However pure hydrogels often have some limitations such as low mechanical

stability and gel strength. In recent years, the creation of nanocomposite hydrogels (NCH)

has been gained one of the effective solutions to overcome these limitations. The inorganic component

in composite hydrogels as second phase can be metallic nanoparticles, oxides or clays minerals.

Within these groups, clay minerals have received more attention due to their unique properties such

as consists of relatively stable aqua silicates of aluminum, iron and magnesium with layered, layeredtape

and mixed-layered structures. Despite the potential advantages of the nanomaterials mentioned

above, some are inherently unstable under normal conditions; therefore their preparation requires

special techniques for formulation at the nanoscale. It is closely related to the interactions between

the polymer matrix and clay nanolayers. Therefore, exfoliating of clay minerals to nanolayers is crucial

to successful production of NCH.

In this paper, the fundamental and recent developments related to NCH are reviewed.