Cobalt(II), Zinc(II) and Nickel(II) coordination polymers constructed by Bis(isophthalate) and Bis(imidazole) derivatives

YILMAZ E., ARICI M., ERER H., YEŞİLEL O. Z.

Polyhedron, cilt.275, 2025 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 275
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1016/j.poly.2025.117529
  • Dergi Adı: Polyhedron
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica
  • Anahtar Kelimeler: 1, 4-bis(2-methyl-imidazol-1-yl-methyl)benzene, 4-diylbis(oxy))diisophthalic acid, 5, 5′-(but-2-en-1, Cobalt(II) complex, Coordination Polymers, Zinc(II) complex and Nickel(II) complex
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Three new heteroleptic coordination polymers, namely, [Co2(μ4-L)(μ-pbmix)2]n (1), [Zn2(μ4-L)(μ-pbmix)2]n (2), and [Ni2(μ4-L)(μ-pbmix)2]n (3) (H4L = 5,5′-(but-2-en-1,4-diylbis(oxy))diisophthalic acid, pbmix = 1,4-bis(2-methyl-imidazol-1-yl-methyl)benzene (pbmix)), were solvothermally synthesized through the reaction of H4L and pbmix with cobalt(II), nickel(II), and zinc(II) nitrates. Their structures were characterized by elemental analysis, FT-IR spectroscopy, and single crystal X-ray diffraction. The thermal properties and phase purities of 1–3 were investigated using thermal analysis techniques (TG and DTA) and powder X-ray diffraction (PXRD). Complexes 1 and 2 are isostructural, exhibiting 3D frameworks with a point symbol of 86. Complex 3 features a 2D network structure with a kgm topology and point symbol of {32.62.72}. Additionally, the luminescence property of compound 2 was investigated.