Selective betainisation of tertiary amine methacrylate block copolymers

BÜTÜN V., Bennett C., Vamvakaki M., Lowe A., Billingham N., Armes S.

JOURNAL OF MATERIALS CHEMISTRY, cilt.7, sa.9, ss.1693-1695, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 7 Sayı: 9
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1039/a703566g
  • Dergi Adı: JOURNAL OF MATERIALS CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1693-1695
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

2-(Dimethylamino)ethyl methacrylate (DMAEMA) was block copolymerised in turn with three other tertiary amine methacrylate comonomers using group transfer polymerisation; the DMAEMA residues of each of these diblock copolymers were selectively betainised using propane-1,3-sultone under mild conditions to yield a series of novel water-soluble sulfobetaine block copolymers which exhibit reversible pi-I-and temperature-induced micellisation.