An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)12NH 2)Ni(CN)4·G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl)


Şenyel M., Sertbakan T. R. , Kürkcüoǧlu G. S. , KASAP E., Kantarci Z.

Journal of Inclusion Phenomena, vol.39, pp.175-180, 2001 (Journal Indexed in SCI Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 39
  • Publication Date: 2001
  • Doi Number: 10.1023/a:1008141726024
  • Title of Journal : Journal of Inclusion Phenomena
  • Page Numbers: pp.175-180

Abstract

Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminododecane) Ni(CN)4·G (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1.12-diaminododecane molecules in the host lattice permit the inclusion of bulky guest molecules. The spectral features suggest that these compounds are similar in structure to the other Hofmann-diam-type clathrates.