Further computations on the solubility of 2-methyl-1,3-benzothiazol-5-amine in ethanol plus water mixtures at several temperatures
PHYSICS AND CHEMISTRY OF LIQUIDS, cilt.58, sa.4, ss.421-431, 2020 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 58 Sayı: 4
- Basım Tarihi: 2020
- Doi Numarası: 10.1080/00319104.2019.1597358
- Dergi Adı: PHYSICS AND CHEMISTRY OF LIQUIDS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Chimica, Compendex, INSPEC, Metadex
- Sayfa Sayıları: ss.421-431
- Eskişehir Osmangazi Üniversitesi Adresli: Evet
Özet
The recently reported solubility data of 2-methyl-1,3-benzothiazol-5-amine in the binary mixtures of {ethanol (1) + water (2)} at various temperatures have been used to present further numerical calculations and thermodynamic analysis. In this regard, the Jouyban-Acree, combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K), Jouyban-Acree-van't Hoff, Yalkowsky and modified Wilson models were used to correlate the solubility data. In addition, the prediction based on the minimum number of experimental data were examined by Jouyban-Acree-van't Hoff and extended Yalkowsky models as well as trained version of Jouyban-Acree model presented in our previous research. Finally, the thermodynamic functions, apparent Gibbs free energy, enthalpy and entropy of the dissolution were calculated based on the van't Hoff equation.