Coordination polymers based on 3,3-dimethylglutarate and 1,4-bis((1H-i-midazol-1-yl)methyl)benzene: Hydrothermal synthesis and characterizations

ARICI M., ERER H., Karacam S., YEŞİLEL O. Z.

JOURNAL OF SOLID STATE CHEMISTRY, vol.277, pp.811-818, 2019 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 277
  • Publication Date: 2019
  • Doi Number: 10.1016/j.jssc.2019.07.043
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.811-818
  • Keywords: 3,3-Dimethylglutarate complexes, 1,4-bis(imidazol-1ylmethyl)benzene complexes, Coordination polymers, Interpenetrated framework, BIS(IMIDAZOLE) LIGANDS, CRYSTAL-STRUCTURES, ALIPHATIC DICARBOXYLATE, STRUCTURAL VARIATION, STERIC BULK, ACID, CONSTRUCTION, ADSORPTION, SEPARATION, MOLECULE
  • Eskisehir Osmangazi University Affiliated: Yes


In this extensive study, four coordination polymers, [Cu(mu (4)-dmg)(mu-pbix)(0.5)](n) (1), {[Cu(mu-dmg)(mu-pbix)] center dot 2H(2)O}(n) (2), {[Zn-2(mu-dmg)(mu-SO4)(mu-pbix)(2)] center dot H2O}(n) (3) and {[Cd(mu-dmg)(H2O)(mu-pbix)] center dot H2O}(n) (4) were synthesized with hydrothermal methods by using 3,3-dimethylglutarate (dmg) and 1,4-bis(imidazol-1ylmethyl)benzene (pbix). The complexes were characterized by elemental analyses, IR spectroscopy and single crystal X-ray diffraction techniques. Single crystal X-ray results demonstrated that complex 1 displayed a 2D network. In the synthesis of 2, Cu(CH3COO)(2) center dot H2O was used instead of Cu(NO3)(2) center dot 3H(2)O and a structurally different complex 2 was obtained with a 2-fold interpenetrated 3D framework (cds topology). Complexes 3 and 4 were interpenetrated with each other to form 3D+3D -> 3D frameworks with bbe-3,4-Cmmm and cds topologies, respectively. The dmg ligand exhibited a new coordination mode, mu-eta(1):eta(1):eta(0):eta(1). Thermal behaviors, photoluminescence and topological properties of the complexes were also investigated.