mer-diaquabis(1H-imidazole-kappa N-3)[orotato(2-)]cobalt(II)

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Atıf İçin Kopyala

YEŞİLEL O. Z., Olmez H., Arici C.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.63, 2007 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 63
• Basım Tarihi: 2007
• Doi Numarası: 10.1107/s0108270107018021
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In the title complex, mer-diaqua[2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylato(2-)]bis(1H-imidazole-kappa N-3)cobalt(II), [Co(C5H2N2O4)(C3H4N2)(2)(H2O)(2)], the Coll ion is coordinated by a deprotonated N atom and the carboxylate O atom of the orotate ligand, two imidazole N atoms and two aqua ligands in a distorted octahedral geometry. The title complex exists as discrete doubly hydrogen-bonded dimers, and a three-dimensional network of O-H...O and N-H...O hydrogen bonds and weak pi-pi interactions is responsible for crystal stabilization.