Synthesis, structural characterization and microbial activity of 2D Ag(I)-5-aminoisophthalate coordination polymer with a new coordination mode

Gunay H., ÇOLAK A. T., YEŞİLEL O. Z., Tunc T., ÇOLAK F.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1099, ss.108-113, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1099
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.molstruc.2015.06.029
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.108-113
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In this study, a novel polynuclear Ag(I)-5-aminoisophthalate complex [Ag(mu(4)-Haip)](n) (1) (H(2)aip = 5-aminoisophthalic acid) has been synthesized. The molecular structure of this complex has been determined by the single crystal X-ray diffraction. The two-dimensional polynuclear complex is crystallized in the triclinic crystal system with space group P-1. The Ag(I) ion is four-coordinated by three carboxylate oxygen atoms of three different Haip ligands and one nitrogen atom in a distorted tetrahedral geometry. Furthermore, a novel coordination mode has shown by H(2)aip. This complex exhibits photoluminescence in the solid state at room temperature. Antimicrobial activity of complex was evaluated by the agar diffusion method. The complex showed antimicrobial activity against tested microorganism strains (Gram positive, gram negative bacteria, clinic isolate yeast and mold). Moreover this complex showed particularly high antifungal activity against yeast and mold. 0 (C) 2015 Elsevier B.V. All rights reserved.