The formation and structure of some androstane 4-and 6-ketones
JOURNAL OF CHEMICAL RESEARCH, sa.4, ss.258-259, 1999 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 1999
- Doi Numarası: 10.1039/a900022d
- Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Metadex
- Sayfa Sayıları: ss.258-259
- Eskişehir Osmangazi Üniversitesi Adresli: Hayır
Özet
The preparation of some substituted androstane 4- and 6-ketones is described revealing further examples of neighbouring group participation between substituents at C-4 and C-6; the X-ray crystal structure of androstane-4,6,17-trione showed that it existed in a form that was a hybrid of the Delta(4)- and Delta(6)-enolates.