Synthesis and aqueous solution properties of novel hydrophilic-hydrophilic block copolymers based on tertiary amine methacrylates

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BÜTÜN V., Billingham N., Armes S.

CHEMICAL COMMUNICATIONS, no.7, pp.671-672, 1997 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: Issue: 7
• Publication Date: 1997
• Doi Number: 10.1039/a700772h
• Journal Name: CHEMICAL COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.671-672
• Eskisehir Osmangazi University Affiliated: Yes

Abstract

A series of near-monodisperse novel diblock copolymers based on tertiary amine methacrylates has been synthesised using group transfer polymerisation chemistry; subtle differences in basicity between the two blocks lead to interesting aqueous solution behaviour, including pH-induced micellisation and very high surface activity.