A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.23, sa.2, ss.418-423, 2013 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 23 Sayı: 2
- Basım Tarihi: 2013
- Doi Numarası: 10.1007/s10904-012-9798-1
- Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.418-423
- Eskişehir Osmangazi Üniversitesi Adresli: Evet
Özet
In this study, a novel organic-inorganic hybrid compound with AgNO3 and 2,3-pyridinedicarboxylic acid (H(2)pydc), [Ag-2(mu(6)-pydc)](n) (1) has been synthesized. The molecular structure of complex has been determined by the single crystal X-ray diffraction. The complex has been observed to crystallize in the monoclinic space group P2(1)/c. The asymmetric unit of compound consists of two crystallographically different Ag(I) centers and one pydc ligand. The Ag1 and Ag2 adopt tetrahedral and T-shaped geometries, respectively. At the same time, the silver(I) compound consists of a fish bone similar to the 1D silver cluster. Furthermore, novel coordination mode shown by H(2)pydc indicates that the crystal exhibits photoluminescence in the solid state at room temperature.