A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate

ÇOLAK, ALPER; Pamuk, Gonul; Uzun, Nazli; YEŞİLEL, OKAN; SEMERCİ, FATİH; Gunay, Handan; BÜYÜKGÜNGÖR, ORHAN

doi:10.1007/s10904-012-9798-1

A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate

Atıf İçin Kopyala

ÇOLAK A. T., Pamuk G., Uzun N., YEŞİLEL O. Z., SEMERCİ F., Gunay H., ...Daha Fazla

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.23, sa.2, ss.418-423, 2013 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 23 Sayı: 2
Basım Tarihi: 2013
Doi Numarası: 10.1007/s10904-012-9798-1
Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.418-423
Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In this study, a novel organic-inorganic hybrid compound with AgNO3 and 2,3-pyridinedicarboxylic acid (H(2)pydc), [Ag-2(mu(6)-pydc)](n) (1) has been synthesized. The molecular structure of complex has been determined by the single crystal X-ray diffraction. The complex has been observed to crystallize in the monoclinic space group P2(1)/c. The asymmetric unit of compound consists of two crystallographically different Ag(I) centers and one pydc ligand. The Ag1 and Ag2 adopt tetrahedral and T-shaped geometries, respectively. At the same time, the silver(I) compound consists of a fish bone similar to the 1D silver cluster. Furthermore, novel coordination mode shown by H(2)pydc indicates that the crystal exhibits photoluminescence in the solid state at room temperature.