Synthesis, IR spectrum, thermal analysis, and crystal structure of the cyano-bridged heteronuclear polymeric complex: [Zn(teta)Ni(μ-CN) 2(CN)2]n

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Atıf İçin Kopyala

Kuerkcueoglu G. S., YEŞİLEL O. Z., Kavlak I., Bueyuekguengoer O.

Zeitschrift fur Anorganische und Allgemeine Chemie, cilt.635, sa.1, ss.175-178, 2009 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 635 Sayı: 1
• Basım Tarihi: 2009
• Doi Numarası: 10.1002/zaac.200800337
• Dergi Adı: Zeitschrift fur Anorganische und Allgemeine Chemie
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.175-178
• Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

The heteronuclear polymeric complex, [Zn(teta)Ni(μ-CN) 2(CN)2]n (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P21/c and in which the ZnII ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the NiII ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30-600°C in the static air atmosphere. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.