A New Tripodal Zwitterionic Ligand-Based Cationic Manganese(II) Metal-Organic Framework: Synthesis, Characterization and Photochromic Property

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Ciftci E., Arici M., Wriedt M., YEŞİLEL O. Z.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, vol.34, no.6, pp.2410-2417, 2024 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 6
  • Publication Date: 2024
  • Doi Number: 10.1007/s10904-023-02973-6
  • Journal Name: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Page Numbers: pp.2410-2417
  • Keywords: Coordination polymers, Interlocked complex, Manganese(II) complex, Photochromism, Zwitterionic ligand
  • Eskisehir Osmangazi University Affiliated: Yes

Abstract

A new flexible tripodal 1,1 ',1 ''-(((1,3,5-triazin-2,4,6-triyl)tris(benzene-4,1-diyl))tris(methylene))tris(3-carboxypyridin-1-ium) bromide (H3taznaBr3) ligand and its new Manganese(II) compound, namely {[Mn(mu 6-tazna)]Cl2 center dot 4H2O}n(OGU - 1, OGU: Osmangazi University), were synthesized and structurally characterized by IR spectroscopy, elemental analysis, X-ray single-crystal and powder diffraction techniques. Single crystal X-ray diffraction analysis revealed that the OGU - 1 is 3D framework, possessing 1D channels along the b-axis with dimensions of 9.39 x 13.63 angstrom 2, in which 1D channels are filled with chloride ions and lattice water molecules. The OGU - 1 displayed a 6,6-connected net with a point symbol of {48.66.8}{49.66}. Furthermore, thermal (TG, DTA and DTA) and photochromic properties of the OGU - 1 were investigated and it exhibited color change under 365 nm UV light.