Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2’,3’-D) pyrrole derivative


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Kivrak A. , Yildiz H. B. , Gökyer S., Bezgin Çarbaş B.

Turkish Journal of Chemistry, cilt.42, sa.2, ss.439-447, 2018 (SCI Expanded İndekslerine Giren Dergi) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Konu: 2
  • Basım Tarihi: 2018
  • Doi Numarası: 10.3906/kim-1709-33
  • Dergi Adı: Turkish Journal of Chemistry
  • Sayfa Sayıları: ss.439-447

Özet

© TÜBITAK.A novel alkoxy-bridged dithieno (3, 2-B:2’,3’-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2’,3’-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The effects of alkoxy bridge in the structure on the electrochemical and spectroelectrochemical properties of the polymer were also investigated in detail. The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.