Synthesis, spectral, thermal and structural characterization of mer-triaquaorotatoquinoxaline cadmium(II) dihydrate

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Atıf İçin Kopyala

YEŞİLEL O. Z., Pasaoglu H., Akdag K., Bueyuekguengoer O.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, cilt.633, sa.10, ss.1731-1734, 2007 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 633 Sayı: 10
• Basım Tarihi: 2007
• Doi Numarası: 10.1002/zaac.200700165
• Dergi Adı: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1731-1734
• Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

The new orotate complex of cadmium(11) with quinoxaline, mer-[Cd(HOr)(H2O)(3)(QX)]center dot 2H(2)O, was synthesized and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the triclinic system, space group P (1) over bar. The Cd2+ ion exhibits a distorted octahedral coordination by one bidentate orotate, one monodentate quinoxaline and three aqua ligands. The uncoordinated water molecules link the orotate, quidoxaline and