Investigation of Supporting Electrolyte Effect on Supercapacitor Properties of Poly(Carbazole) Films

Duran B., Unver I. C., Bereket G.

JOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY, cilt.11, ss.41-49, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 11
  • Basım Tarihi: 2020
  • Doi Numarası: 10.33961/jecst.2019.00129
  • Dergi Adı: JOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.41-49
  • Anahtar Kelimeler: Electropolymerization, Polycarbazole, Cyclic Voltammetry, EIS, ELECTROCHEMICAL CAPACITORS, DOPED POLY(3-METHYLTHIOPHENE), CARBON NANOTUBES, SULFONIC-ACID, POLYPYRROLE, POLYANILINE, COMPOSITE, POLYTHIOPHENE, PERFORMANCE, BEHAVIOR
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

In this study poly(carbazole) films deposited on stainless steel have been investigated as electrode material for supercapacitor applications. Poly(carbazole) films were electrodeposited using cyclic voltammetry in presence of lithium, sodium and tetrabutylammonium perchlorate salts. Poly(carbazole) films doped with perchlorate anions having different counter cations were characterized by SEM, ATR-FTIR and solid state conductivity measurements. Capacitive behaviours of PCz coated steel electrodes were tested by cyclic voltammetry, charge-discharge analysis and electrochemical impedance spectroscopy. It was found that counter cation of the dopant is significantly effective on the capacitive performance on the obtained PCz films and the PCz film synthesized from lithium perchlorate has the better capacitive performance than the poly(carbazole)s synthesized from sodium perchlorate and tetrabutylammonium perchlorate salts.