A series of three dimensional lanthanoid(III)-metal-organic frameworks with zwitterionic linker

Aghamohammadi P., ARICI M., Büyükgüngör O., Wriedt M., YEŞİLEL O. Z.

JOURNAL OF COORDINATION CHEMISTRY, cilt.74, sa.16, ss.2657-2669, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 74 Sayı: 16
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1080/00958972.2021.2001804
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Metadex
  • Sayfa Sayıları: ss.2657-2669
  • Anahtar Kelimeler: Zwitterionic complexes, lanthanoid complexes, 3D complexes, coordination polymers, METAL-ORGANIC FRAMEWORKS, COORDINATION POLYMERS, HYDROGEN ADSORPTION, POROUS MATERIALS, NIR EMISSION, CO2 CAPTURE, WHITE-LIGHT, LN-MOFS, PHOTOLUMINESCENCE, LIGAND
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

A series of isostructural 3D lanthanoid coordination polymers, {[Ln(mu(4)-cbpy)(2)]Br center dot xsolvent}(n) (Ln = La(1), Pr(2), Nd(3), Sm(4), Gd(5), Tb(6), Dy(7) and Ho(8), (H(2)cbpy)Br = 4-carboxy-1-(4-carboxybenzyl)pyridinium bromide), have been solvothermally synthesized and characterized by single-crystal X-ray diffraction, IR and elemental analysis. Powder X-ray diffraction (PXRD) and thermal analyses (TG, DTA and DTA) of 1-8 were also investigated. The single crystal X-ray diffraction analyses revealed that 1-8 were isostructural and crystallized in the monoclinic space group C2/c. In the complexes, each cbpy(-) acts as a tetrakis(monodentate) to connect to four Ln(III) ions. A pair of Ln(III) ions are coordinated by four carboxylate oxygen atoms to form paddle-wheel {Ln(2)(RCOO)(4)} secondary building units which are connected by four cbpy(-) ligand to form a 3D structure with scu topology.