A theoretical application of SEMUT NMR spectroscopy to deuterated compounds
APPLIED MAGNETIC RESONANCE, cilt.20, ss.265-273, 2001 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 20
- Basım Tarihi: 2001
- Doi Numarası: 10.1007/bf03162325
- Dergi Adı: APPLIED MAGNETIC RESONANCE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.265-273
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Eskişehir Osmangazi Üniversitesi Adresli: Hayır
Özet
The product operator formalism is widely used for analytical description of multiple-pulse nuclear magnetic resonance (NMR) experiments for weakly coupled spin systems. C-13 subspectral editing with a multiple quantum trap (SEMUT) NMR spectroscopy is used for subspectral editing of CH3, CH2, CH and C groups. In this study, after obtaining the evolutions of IxSy2 and IySy2 product operators under the spin-spin coupling Hamiltonian for IS (I = 1/2, S = 1) spin system, the product operator technique was applied for the analytical description of C-13 SEMUT NMR for CDn groups. Then, theoretical discussion and experimental suggestions for the subspectral editing of CD3, CD2, CD and C groups are presented.