A theoretical application of SEMUT NMR spectroscopy to deuterated compounds


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Gencten A., Tezel Ö. , Koroglu A.

APPLIED MAGNETIC RESONANCE, vol.20, pp.265-273, 2001 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 20
  • Publication Date: 2001
  • Doi Number: 10.1007/bf03162325
  • Title of Journal : APPLIED MAGNETIC RESONANCE
  • Page Numbers: pp.265-273

Abstract

The product operator formalism is widely used for analytical description of multiple-pulse nuclear magnetic resonance (NMR) experiments for weakly coupled spin systems. C-13 subspectral editing with a multiple quantum trap (SEMUT) NMR spectroscopy is used for subspectral editing of CH3, CH2, CH and C groups. In this study, after obtaining the evolutions of IxSy2 and IySy2 product operators under the spin-spin coupling Hamiltonian for IS (I = 1/2, S = 1) spin system, the product operator technique was applied for the analytical description of C-13 SEMUT NMR for CDn groups. Then, theoretical discussion and experimental suggestions for the subspectral editing of CD3, CD2, CD and C groups are presented.