Recovery of acetic acid from waste streams by extractive distillation


Demiral H., Yildirim M.

WATER SCIENCE AND TECHNOLOGY, vol.47, no.10, pp.183-188, 2003 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 47 Issue: 10
  • Publication Date: 2003
  • Journal Name: WATER SCIENCE AND TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.183-188
  • Keywords: acetic acid, extractive distillation, recovery
  • Eskisehir Osmangazi University Affiliated: Yes

Abstract

Wastes have been considered to be a serious worldwide environmental problem in recent years. Because of increasing pollution, these wastes should be treated. However, industrial wastes can contain a number of valuable organic components. Recovery of these components is important economically. Using conventional distillation techniques, the separation of acetic acid and water is both. impractical and uneconomical, because it often requires large number of trays and a high,reflux ratio. In practice special techniques are used depending on the concentration of acetic acid. Between 30 and 70% (w/w) acetic, acid contents, extractive distillation was suggested. Extractive distillation is a multicomponent-rectification method similar in purpose to azeotropic distillation. In extractive distillation, to a binary mixture which is difficult or impossible to separate by ordinary means, a third component termed an entrainer is added which alters the relative Volatility of the original constituents, thus permitting the separation. In our department acetic acid is used as a solvent during the obtaining of cobalt(III) acetate from cobalt(II) acetate by an electrochemical method. After the operation, the remaining waste contains acetic acid: In this work, acetic acid which has been found in this waste was recovered by extractive distillation. Adiponitrile and sulfolane were used as high boiling solvents and the effects of solvent feed rate/solution feed rate ratio and solvent type were investigated. According to the experimental results, it was seem that the recovery of acetic acid from waste streams is possible by extractive distillation.