EPR spectra of Cu2+ doped [Zn(sac)(2)(dmen)] and [Zn(sac)(2)(paen)] single crystals

Biyik, R.; Tapramaz, R.; YEŞİLEL, OKAN

doi:10.1016/j.saa.2006.12.008

EPR spectra of Cu2+ doped [Zn(sac)(2)(dmen)] and [Zn(sac)(2)(paen)] single crystals

Atıf İçin Kopyala

Biyik R., Tapramaz R., YEŞİLEL O. Z.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.68, sa.2, ss.394-398, 2007 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 68 Sayı: 2
Basım Tarihi: 2007
Doi Numarası: 10.1016/j.saa.2006.12.008
Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.394-398
Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Cu2+ doped single crystals of [Zn(sac)(2)(dmen)] (sac: saccharinate, dmen: NAP-dimethylethylendiamine) and [Zn(sac)(2)(paen)], (paen: NAP-bis(3-propylamine)ethylendiamine) complexes have been investigated by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra indicate that Cu2+ ion substitute with Zn2+ ion and forms tetrahedral complex in [Zn(sac)(2)(dmen)] and octahedral complex in [Zn(sac)(2)(paen)] hosts. Principal values of the g and hyperfine tensors are determined and the ground state wave functions of Cu2+ ions are obtained using EPR parameters. (C) 2006 Elsevier B.V. All rights reserved.