Novel and Efficient Methods for the Synthesis of Symmetrical Trisulfides

Kertmen A., Lach S., Rachon J., Witt D.

SYNTHESIS-STUTTGART, sa.9, ss.1459-1462, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 9
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1055/s-0028-1088161
  • Dergi Adı: SYNTHESIS-STUTTGART
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1459-1462
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

We have developed convenient methods for the synthesis of symmetrical trisulfides under mild conditions in very good yields. The described methods are based oil the straightforward preparation of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorin-2-yl)disulfanyl derivatives from readily available 5,5-dimethyl-2-sulfanyl-2-thioxo-1,3,2-dioxaphosphorinane or bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl) disulfide. The symmetrical trisulfides can be obtained from aliphatic and aromatic thiols and also L-cysteine derivatives.