Synthesis and aqueous solution properties of a well-defined thermo-responsive schizophrenic diblock copolymer

Weaver J., Armes S., BÜTÜN V.

CHEMICAL COMMUNICATIONS, sa.18, ss.2122-2123, 2002 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Konu: 18
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1039/b207251n
  • Sayfa Sayıları: ss.2122-2123


We report only the second example of a thermo-responsive 'schizophrenic' diblock copolymer surfactant: unlike the original (meth)acrylamide-based example reported by Laschewsky and co-workers (J. Am. Chem. Soc., 2002, 124, 3787), this new methacrylate-based diblock copolymer is near-monodisperse, readily synthesized in high yield and exhibits a broad temperature range between the two micelle transitions.