The novel polymeric potassium complex with a new coordination mode of orotic acid [K(mu(5)-H(2)Or)(mu-H2O)](n): Synthesis and structural characterization

YEŞİLEL O. Z., Kastas G., Bueyuekguengoer O.

INORGANIC CHEMISTRY COMMUNICATIONS, vol.10, no.8, pp.936-939, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 10 Issue: 8
  • Publication Date: 2007
  • Doi Number: 10.1016/j.inoche.2007.05.003
  • Journal Name: INORGANIC CHEMISTRY COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.936-939
  • Eskisehir Osmangazi University Affiliated: Yes

Abstract

Novel polynuclear seven-coordinated potassium complex, [K(mu(5)-H(2)Or)(mu-H2O)](n)(H(3)Or = orotic acid), with the new coordination mode of orotic acid has been prepared and characterized by elemental analysis, FT-IR spectra, X-ray diffraction. The orotate ligand exhibits new coordination mode of mu 5-kappa O, O: kappa O', O': O'' for H(2)Or(-). (c) 2007 Elsevier B.V. All rights reserved.