Electrochemical synthesis and anti-corrosive properties of polyaniline, poly(2-anisidine), and poly(aniline-co-2-anisidine) films on stainless steel

Bereket G., Hur E., ŞAHİN Y.

PROGRESS IN ORGANIC COATINGS, cilt.54, sa.1, ss.63-72, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Derleme
  • Cilt numarası: 54 Sayı: 1
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.porgcoat.2005.06.002
  • Dergi Adı: PROGRESS IN ORGANIC COATINGS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.63-72
  • Anahtar Kelimeler: conducting polymer, polyaniline, polyanisidine, corrosion, steel, electropolymerization, MILD-STEEL, CORROSION PROTECTION, CONDUCTING POLYMERS, OXIDIZABLE METALS, ZINC ELECTRODES, THIN-FILMS, ELECTROPOLYMERIZATION, POLYPYRROLE, COATINGS, IRON
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Stable and adherent polymer films of polyaniline and of poly(2-anisidine) were grown on 304-stainless steel by cyclic voltammetry in tetrabutylammonium perchlorate/acetonitrile solution containing perchloric acid. Conducting poly(aniline-co-2-anisidine) was also formed on 304-stainless steel in same condition, but the film was unstable and peeled off after 3 h when it is immersed in aggressive solution. The structure and properties of these polymer films were characterized by FTIR and UV-vis spectroscopy and by electrochemical methods. The anti-corrosion behavior of polyaniline, poly(2-anisidine), and poly(aniline-co-2-anisidine) coated electrodes were investigated in 0.5 M hydrochloric acid solutions by potentiodynamic polarization technique, open circuit potential-time curves and electrochemical impedance spectroscopy. Poly(2-anisidine) film shows protection against corrosion 304-stainless steel in 0.5 M HCI by passivating steel substrate in similar manner as has been observed for polyaniline. But anti-corrosion behavior was slightly poorer than that of polyaniline. (c) 2005 Elsevier B.V. All rights reserved.