The oxidation of some steroidal dienes and trienes with chromic acid
JOURNAL OF CHEMICAL RESEARCH-S, sa.10, ss.594-598, 1999 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 1999
- Doi Numarası: 10.1039/a904215f
- Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.594-598
- Eskişehir Osmangazi Üniversitesi Adresli: Hayır
Özet
The chromic acid oxidation of steroidal 2,4- and 3,5-dienes and 2,4,6-trienes is shown to take place at the secondary termini of the alkenes rather than at the allylic positions and is rationalized in terms of a sequence of 1:4-additions of chromic acid.