The oxidation of some steroidal dienes and trienes with chromic acid

Hanson J., KIRAN İ.

JOURNAL OF CHEMICAL RESEARCH-S, sa.10, ss.594-598, 1999 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1039/a904215f
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.594-598
  • Eskişehir Osmangazi Üniversitesi Adresli: Hayır

Özet

The chromic acid oxidation of steroidal 2,4- and 3,5-dienes and 2,4,6-trienes is shown to take place at the secondary termini of the alkenes rather than at the allylic positions and is rationalized in terms of a sequence of 1:4-additions of chromic acid.