The Influence of UV Radiation Aging on Degradation of Shear Thickening Fluids

Zurowski R., Tryznowski M., GÜRGEN S., Szafran M., Swiderska A.

MATERIALS, cilt.15, sa.9, 2022 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 15 Sayı: 9
  • Basım Tarihi: 2022
  • Doi Numarası: 10.3390/ma15093269
  • Dergi Adı: MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, CAB Abstracts, Communication Abstracts, Compendex, INSPEC, Metadex, Veterinary Science Database, Directory of Open Access Journals, Civil Engineering Abstracts
  • Anahtar Kelimeler: shear thickening fluids, aging, lightfastness, product degradation, BALLISTIC PERFORMANCE, COMPOSITES, ABSORPTION, IMPACT
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

Shear thickening fluids (STFs) are innovative materials that can find applications in smart body armor. However, the usage of STFs is limited by the aging of these materials. This work aims to analyze the influence of UV radiation on the aging process of STFs. The investigation was done experimentally, and artificial aging was applied to investigate the impact of UV radiation on the properties of STFs. The shear-thickening properties of obtained STFs were confirmed by viscosity measurements. The STFs based on PPG425, PPG2700, and KE-P10 exhibited a very high maximum viscosity of up to 580.7 Pa center dot s and 3313 Pa center dot s for the STF425 and STF2700, respectively. The aging of the obtained STFs caused the liquid matrix degradation, causing damage to the STFs and their change from liquid into solid. Furthermore, the FT-IR, H-1 NMR, and C-13 NMR spectroscopies were used for the confirmation of the breakdown of STFs. The FT-IR spectroscopy revealed the appearance of carbonyl groups in STFs after aging. Moreover, H-1 NMR and C-13 NMR spectroscopy confirmed the formation of the typical groups containing carbonyl groups. Our results demonstrate that STFs are UV light-sensitive and may lose their properties during storage.