Tailoring ZrWNb-Based Refractory High Entropy Alloys: A Multidirectional Characterization Through Elemental, Physical, Thermodynamic, and Nuclear Radiation Attenuation Properties

Güler Ö., Özkul İ., Almisned G., Şen Baykal D., Alkarrani H., Kılıç G., ...Daha Fazla

NUCLEAR TECHNOLOGY, cilt.12, ss.1-23, 2024 (SCI-Expanded)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 12
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/00295450.2024.2411791
  • Dergi Adı: NUCLEAR TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, Metadex, Pollution Abstracts, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1-23
  • Eskişehir Osmangazi Üniversitesi Adresli: Evet

Özet

This study explores the development and characterization of 18 novel ZrWNb[(X)(Y)] (where XY are Hf, Ta, Mo, V, Ti) refractory high entropy alloys (RHEAs) designed to enhance mechanical robustness, thermodynamic stability, and radiation shielding effectiveness. Through a rigorous analysis, we evaluated the elastic modulus, entropy, and enthalpy of mixing, atomic size difference, valence electron concentration, and the omega parameter to understand the alloys’ phase behavior and structural integrity. Our findings revealed a broad range of elastic modulus values, indicating diverse mechanical adaptability suitable for high-stress applications. The thermodynamic assessment highlighted several RHEAs with favorable phase stability, particularly ZrWNbTaHf and ZrWNbTiTaHf, which are poised for high-performance usage due to their balanced mixing entropy and enthalpy.

This study also benchmarks the RHEAs against conventional alloys, with sample R1 exhibiting the lowest fast neutron effective removal cross section, underscoring its superior neutron shielding capabilities. Additionally, R1 demonstrated exceptional photon attenuation, as evidenced by its competitive half-value layer performance across an extensive energy spectrum. Collectively, these results position R1 as a standout candidate, offering a significant advancement in materials science for applications demanding stringent radiation shielding, such as in nuclear reactor environments and space exploration.