EPR studies of Cu2+-doped bis(saccharinato)bis(pyridine)zinc(II) single crystals
APPLIED MAGNETIC RESONANCE, cilt.26, sa.3, ss.275-282, 2004 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 26 Sayı: 3
- Basım Tarihi: 2004
- Doi Numarası: 10.1007/bf03166801
- Dergi Adı: APPLIED MAGNETIC RESONANCE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.275-282
- Eskişehir Osmangazi Üniversitesi Adresli: Hayır
Özet
The electron paramagnetic resonance spectra of Cu2+ impurities in bis(saccharinato)bis(pyridine)zinc(H) single crystals have been studied at room temperature in three mutually perpendicular planes. The angular variation of the spectra indicates the substitution of the host Zn2+ with Cu2+. Two magnetically inequivalent sites for Cu2+ have been observed. The spectra were fitted to the rhombic spin Hamiltonian. The spin Hamiltonian parameters and the molecular orbital coefficients were evaluated for the two sites. The ground-state wave function of Cu2+ ion in the lattice has been constructed.