Synthesis, characterization, optical and electrochemical performances of 3-fold interpenetrated Copper(II) coordination polymer with a flexible zwitterionic ligand

Çiftçi E., ARICI M., Demir E., Demir-Cakan R., Wriedt M., YEŞİLEL O. Z.

Journal of Solid State Chemistry, vol.302, 2021 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 302
  • Publication Date: 2021
  • Doi Number: 10.1016/j.jssc.2021.122375
  • Journal Name: Journal of Solid State Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Chemical Abstracts Core, Chimica, Compendex, INSPEC, Metadex
  • Keywords: Coordination polymer, 1,1'-([1,1'-biphenyl]-4,40-diylbis(methylene)), bis(3-carboxypyridin-1-ium compound, Zwitterionic compound, Copper(II) compound and Li-Ion battery, METAL-ORGANIC FRAMEWORKS, LI-ION, CRYSTAL-STRUCTURES, ANODE MATERIALS, COMPOSITES, ELECTRODES, CONVERSION, BATTERIES
  • Eskisehir Osmangazi University Affiliated: Yes


© 2021 Elsevier Inc.A new Cu(II)-coordination polymer, formulated as {[CuCl(μ4-bipna)](NO3)·2.5H2O}n (1) ((H2bipna)Br2: 1,1'-([1,1′-biphenyl]-4,4′-diylbis (methylene))bis (3-carboxypyridin-1-ium) bromide) was synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction technique. The single crystal X-ray diffraction analysis revealed that compound 1 exhibited a 2D→2D polycatenane of 3-fold interpenetrated sql layers. The electrochemical performance of 1 was performed both as anode and cathode for Li-ion batteries. In both situations, the capacity values remained around 20–40 mAhg−1 independent of type of the electrodes. In addition, the thermal and optical properties of compound 1 were investigated.