Syntheses and characterizations of tetracyanoplatinate(II) complexes with 2-pyridineethanol

Sayin E., KÜRKÇÜOĞLU G. S., YEŞİLEL O. Z., HÖKELEK T.

JOURNAL OF COORDINATION CHEMISTRY, vol.68, no.13, pp.2271-2285, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 68 Issue: 13
  • Publication Date: 2015
  • Doi Number: 10.1080/00958972.2015.1048239
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2271-2285
  • Keywords: Tetracyanoplatinate(II) complex, 2-Pyridineethanol complex, Heteronuclear complex, Cyanide-bridged complex, 1-D complex, LOW-DIMENSIONAL COMPOUNDS, PI-PI STACKING, POLYMERIC COMPLEXES, THERMAL-PROPERTIES, CRYSTAL-STRUCTURE, CYANO, SPECTRA, CU(II), RAMAN
  • Eskisehir Osmangazi University Affiliated: Yes

Abstract

New cyanide-bridged heteronuclear polymeric complexes, [Cu(hepH) 2Pt(mu-CN) 2(CN) 2] n (1), [ Zn (hepH) 2Pt(mu-CN)(2)(CN)(2)] n (2), and [ Cd(hepH)(2)Pt(mu-CN)(2)(CN)(2)] n (3) (2-pyridineethanol abbreviated to hepH), have been synthesized and characterized by elemental analysis, FT-IR and Raman spectroscopies, thermal analysis, and single-crystal X-ray diffraction techniques. Hydrogen bonds play very important roles in the construction of supramolecular structures. From the crystallographic data, it was determined that the crystal packings of 1-3 were composed of rare intermolecular C-H. Pt interactions. In addition, these complexes have p. p and O-H. N interactions.