Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2 '-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene

Yaman P. K., ERER H., ARICI M., Erucar I., YEŞİLEL O. Z.

INORGANICA CHIMICA ACTA, vol.488, pp.229-237, 2019 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 488
  • Publication Date: 2019
  • Doi Number: 10.1016/j.ica.2018.12.039
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.229-237
  • Keywords: Coordination polymers, Hydrothermal synthesis method, 2,2 '-Dimethylglutarate complex, 1,2-Bis(imidazol-1-ylmethyl)benzene, METAL-ORGANIC FRAMEWORKS, TOPOLOGICAL ANALYSIS, MAGNETIC-PROPERTIES, SUBSTITUTED GLUTARATE, CRYSTAL-STRUCTURES, LIGANDS SYNTHESIS, BUILDING-BLOCKS, ACID SYNTHESES, 2D, CONSTRUCTION
  • Eskisehir Osmangazi University Affiliated: Yes


The hydrothermal reactions of some metal ions with 2,2'-dimethylglutaric acid (22dmgH(2)) and 1,2-bis(imidazol-1-ylmethyl)benzene (obix) newly afford four coordination polymers are called, {[Co-2 (mu-22dmg)(2)(mu-obix)(2)]center dot 1.5H(2)O}(n) (1), {[Cu(mu-22dmg)(mu-obix)]center dot H2O}(n) (2), {[Zn-2(mu-22dmg)(2)(mu-obix)(2)]center dot 2H(2)O}(n) (3) and [Cd-2(mu-22dmg)(2)(mu-obix)(2)(H2O)](n) (4). All of the complexes were characterized by elemental analysis, IR spectra, single crystal X- ray diffraction, powder X-ray diffraction (PXRD), and thermal analysis techniques. Furthermore, photoluminescence and topological properties were studied. The X-ray single crystal study shows that complexes 1, 3 and 4 display 3-fold parallel interpenetrating networks with hcb topology showing an unusual 2D + 2D + 2D -> 2D structures. Topological analysis reveals that complex 2 has an uninodal 4-c net sql topology with the point symbol of 4(4).6(2). Atomically-detailed simulations were finally performed to compute hydrogen (H-2) uptake in these complexes at 77 K.